Автор: Andrzej Wieckowski Название: Fuel Cell Science: Theory, Fundamentals, and Biocatalysis Издательство: Wiley Год: 2010 ISBN: 9780470410295 Серия: Wiley Series on Electrocatalysis and Electrochemistry Язык: English Формат: pdf Размер: 53,3 mb Страниц: 648
Fuel cell science is undergoing significant development, thanks, in part, to a spectacular evolution of the electrocatalysis concepts, and both new theoretical and experimental methods. Responding to the need for a definitive guide to the field, Fuel Cell Science provides an up-to-date, comprehensive compendium of both theoretical and experimental aspects of the field.
Designed to inspire scientists to think about the future of fuel cell technology, Fuel Cell Science addresses the emerging field of bio-electrocatalysis and the theory of heterogeneous reactions in fuel cell science and proposes potential applications for electrochemical energy production. The book is thorough in its coverage of the electron transfer process and structure of the electric double layer, as well as the development of operando measurements
Foreword vii Preface xi Preface to the Wiley Series on Electrocatalysis and Electrochemistry xiii Contributors xv
1. Hydrogen Reactions on Nanostructured Surfaces 1 Holger Wolfschmidt, Odysseas Paschos, and Ulrich Stimming
2. Comparison of Electrocatalysis and Bioelectrocatalysis of Hydrogen and Oxygen Redox Reactions 71 Marc T. M. Koper and Hendrik A. Heering
3. Design of Palladium-Based Alloy Electrocatalysts for Hydrogen Oxidation Reaction in Fuel Cells 111 Sung Jong Yoo and Yung-Eun Sung
4. Mechanism of an Enhanced Oxygen Reduction Reaction at Platinum-Based Electrocatalysts: Identification and Quantification of Oxygen Species Adsorbed on Electrodes by X-Ray Photoelectron Spectroscopy 147 Mitsuru Wakisaka, Hiroyuki Uchida, and Masahiro Watanabe
5. Biocathodes for Dioxygen Reduction in Biofuel Cells 169 Renata Bilewicz and Marcin Opallo
6. Platinum Monolayer Electrocatalysts: Improving Structure and Activity 215 Kotaro Sasaki, Miomir B. Vukmirovic, Jia X. Wang, and Radoslav R. Adzic
7. The Importance of Enzymes: Benchmarks for Electrocatalysts 237 Fraser A. Armstrong
8. Approach to Microbial Fuel Cells and Their Applications 257 Juan Pablo Busalmen, Abraham Esteve-Nun?ez , and Juan Miguel Feliu
9. Half-Cell Investigations of Cathode Catalysts for PEM Fuel Cells: From Model Systems to High-Surface-Area Catalysts 283 Matthias Arenz and Nenad M. Markovic
10. Nanoscale Phenomena in Catalyst Layers for PEM Fuel Cells: From Fundamental Physics to Benign Design 317 Karen Chan, Ata Roudgar, Liya Wang, and Michael Eikerling
11. Fuel Cells with Neat Proton-Conducting Salt Electrolytes 371 Dominic Gervasio
12. Vibrational Spectroscopy for the Characterization of PEM Fuel Cell Membrane Materials 395 Carol Korzeniewski
13. Ab Initio Electrochemical Properties of Electrode Surfaces 415 Ismaila Dabo, Yanli Li, Nicephore Bonnet, and Nicola Marzari
14. Electronic Structure and Reactivity of Transition Metal Complexes 433 Heather J. Kulik and Nicola Marzari
15. Quantitative Description of Electron Transfer Reactions 457 Patrick H.-L. Sit, Agostino Migliore, Michael L. Klein, and Nicola Marzari
16. Understanding Electrocatalysts for Low-Temperature Fuel Cells 489 Peter Ferrin, Manos Mavrikakis, Jan Rossmeisl, and Jens K. N?rskov
17. Operando XAS Techniques: Past, Present, and Future 511 Christina Roth and David E. Ramaker
18. Operando X-Ray Absorption Spectroscopy of Polymer Electrolyte Fuel Cells 545 Eugene S. Smotkin and Carlo U. Segre
19. New Concepts in the Chemistry and Engineering of Low-Temperature Fuel Cells 565 Fikile R. Brushett, Paul. J. A Kenis, and Andrzej Wieckowski
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